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Mono-, di- and trinuclear zirconium hydride species have been isolated in the treatment of amido complexes [Zr(η5-C5Me5)(NMe2)nCl3-n] (n = 3, 1) with amine-borane adducts NHR2BH3 (R2 = Me2, HtBu). The… Click to show full abstract
Mono-, di- and trinuclear zirconium hydride species have been isolated in the treatment of amido complexes [Zr(η5-C5Me5)(NMe2)nCl3-n] (n = 3, 1) with amine-borane adducts NHR2BH3 (R2 = Me2, HtBu). The reactions involve the formation of amidoborane ligands with ZrH-B interactions which readily undergo β-hydride elimination to give hydride functions.
Keywords:
zirconium hydride;
hydride species;
amido complexes
Journal Title: Dalton transactions
Year Published: 2017
Link to full text (if available)
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Journal Title: Dalton transactions
Year Published: 2017
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!