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A temperature-resolved assembly of a series of the largest scandium-containing polyoxotungstates.

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We report a temperature-resolved assembly of a series of novel nanoscale hexameric Sc-containing polyoxometalates of {Sb6Sc11W60}, {Sb8Sc7W60}, and {Sb8Sc6W60}. These compounds include the largest Sc-containing polyoxotungstates and contain the largest… Click to show full abstract

We report a temperature-resolved assembly of a series of novel nanoscale hexameric Sc-containing polyoxometalates of {Sb6Sc11W60}, {Sb8Sc7W60}, and {Sb8Sc6W60}. These compounds include the largest Sc-containing polyoxotungstates and contain the largest number of Sc3+ ions of any polyoxotungstates reported to date.

Keywords: containing polyoxotungstates; assembly series; resolved assembly; temperature resolved; series largest

Journal Title: Dalton transactions
Year Published: 2017

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