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Determination of zero-field splitting in Co2+ halide complexes with magnetic and far-IR measurements.

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Three penta-coordinate Co2+ complexes with halide substitutes were synthesized. Their zero-field splitting (ZFS) parameters were determined by fitting dc magnetic data and far-infrared magneto-transmission spectra. The results gave an unusual… Click to show full abstract

Three penta-coordinate Co2+ complexes with halide substitutes were synthesized. Their zero-field splitting (ZFS) parameters were determined by fitting dc magnetic data and far-infrared magneto-transmission spectra. The results gave an unusual case that complexes with heavier halide atoms bear smaller ZFS parameters.

Keywords: determination zero; field splitting; zero field; splitting co2; co2 halide

Journal Title: Dalton transactions
Year Published: 2017

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