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Formation of high-molecular weight polyaminoborane by Fe hydride catalysed dehydrocoupling of methylamine borane.

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The complex [(PNHP)Fe(H)(CO)(HBH3)] (PNHP = HN(CH2CH2Pi-Pr2)2) serves as a catalyst precursor for the selective dehydrocoupling of methylamine borane at room temperature, tentatively via an off-metal polymerisation pathway. Click to show full abstract

The complex [(PNHP)Fe(H)(CO)(HBH3)] (PNHP = HN(CH2CH2Pi-Pr2)2) serves as a catalyst precursor for the selective dehydrocoupling of methylamine borane at room temperature, tentatively via an off-metal polymerisation pathway.

Keywords: high molecular; methylamine borane; dehydrocoupling methylamine; formation high

Journal Title: Dalton transactions
Year Published: 2017

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