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Deprotonated meso-hydroxyporphyrin as a stable π-electronic anion: the building unit of an ion-pairing assembly.

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The NiII complex of 5-hydroxy-10,15,20-tris(pentafluorophenyl)-porphyrin was synthesized as the precursor of a negatively charged π-electronic system. Deprotonation, which was examined through UV/vis and 1H NMR spectra, provided an anionic species… Click to show full abstract

The NiII complex of 5-hydroxy-10,15,20-tris(pentafluorophenyl)-porphyrin was synthesized as the precursor of a negatively charged π-electronic system. Deprotonation, which was examined through UV/vis and 1H NMR spectra, provided an anionic species as the building unit of an ion-pairing assembly in combination with an aliphatic cation.

Keywords: building unit; unit ion; pairing assembly; ion pairing

Journal Title: Dalton transactions
Year Published: 2017

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