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A versatile route to homo- and hetero-bimetallic 5f-5f and 3d-5f complexes supported by a redox active ligand framework.

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The salt-elimination reaction of the complex [Na2U(bis-salophen)] with metal halides provides an entry to the synthesis of well-defined homobimetallic uranium-uranium and rare heterobimetallic uranium-cobalt and uranium-nickel complexes supported by a… Click to show full abstract

The salt-elimination reaction of the complex [Na2U(bis-salophen)] with metal halides provides an entry to the synthesis of well-defined homobimetallic uranium-uranium and rare heterobimetallic uranium-cobalt and uranium-nickel complexes supported by a redox-active dinucleating ligand.

Keywords: supported redox; complexes supported; versatile route; route homo; redox active; ligand

Journal Title: Dalton transactions
Year Published: 2017

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