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A mononuclear hexacoordinate complex [Co(pydm)2](dnbz)2 formed from 2,6-pyridinedimethanol in the coordination sphere of Co(ii) and dinitrobenzoato anions exhibits magnetic anisotropy of an easy axis type and a field induced slow… Click to show full abstract
A mononuclear hexacoordinate complex [Co(pydm)2](dnbz)2 formed from 2,6-pyridinedimethanol in the coordination sphere of Co(ii) and dinitrobenzoato anions exhibits magnetic anisotropy of an easy axis type and a field induced slow magnetic relaxation with manifold relaxation channels. The low-frequency relaxation time is as slow as τLF = 0.13 s at BDC = 0.4 T and T = 1.9 K.
Keywords:
relaxation;
mononuclear complex;
relaxation channels;
complex formed;
formed pyridinedimethanol;
manifold
Journal Title: Dalton transactions
Year Published: 2017
Link to full text (if available)
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Journal Title: Dalton transactions
Year Published: 2017
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!