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The metallosupramolecular Ti-based M4L4 cage of [Ti4O2L4Cl8] (L = 4-acetamidobenzoic acid) is synthesized via the one-pot solvothermal reaction of 4-aminobenzoic acid, acetic acid and TiCl4. The Ti(iv) ion functions as… Click to show full abstract
The metallosupramolecular Ti-based M4L4 cage of [Ti4O2L4Cl8] (L = 4-acetamidobenzoic acid) is synthesized via the one-pot solvothermal reaction of 4-aminobenzoic acid, acetic acid and TiCl4. The Ti(iv) ion functions as a Lewis acid catalyst for acylation condensation, and then coordinates with the resultant 4-acetamidobenzoic acid to afford Ti-based cage formation in a cascade fashion.
Keywords:
coordination;
ticl4;
cascade covalent;
formation;
based cage;
cage
Journal Title: Dalton transactions
Year Published: 2018
Link to full text (if available)
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Journal Title: Dalton transactions
Year Published: 2018
Link to full text (if available)
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recommendations!