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A mesoionic nitrogen-donor ligand: structure, iridium coordination, and catalytic effects.

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A mesoinic pyridylideneamide ligand (PYA) was synthetized and fully characterized and coordinated to an iridium(iii) center. This ligand represents the first example of a mesoionic N-donor ligand. Structural and spectroscopic… Click to show full abstract

A mesoinic pyridylideneamide ligand (PYA) was synthetized and fully characterized and coordinated to an iridium(iii) center. This ligand represents the first example of a mesoionic N-donor ligand. Structural and spectroscopic analysis revealed unique properties which were exploited in chemically driven water oxidation catalysis.

Keywords: donor ligand; mesoionic nitrogen; nitrogen donor; iridium; ligand

Journal Title: Dalton transactions
Year Published: 2018

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