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Could new U(ii) complexes be accessible via tuning hybrid heterocalix[4]arene? A theoretical study of redox and structural properties.

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Tuning the building blocks of pyrrole and arene/pyridine in hybrid heterocalix[4]arene allows for the possible accessibility of several intriguing divalent uranium complexes, which are energetically stabilized by enhanced δ(U-Ar) bonds… Click to show full abstract

Tuning the building blocks of pyrrole and arene/pyridine in hybrid heterocalix[4]arene allows for the possible accessibility of several intriguing divalent uranium complexes, which are energetically stabilized by enhanced δ(U-Ar) bonds and further corroborated by computed UIII/II reduction potentials.

Keywords: heterocalix arene; could new; new complexes; hybrid heterocalix

Journal Title: Dalton transactions
Year Published: 2018

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