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A metal-calixarene coordination nanotube with 5-(pyrimidin-5-yl)isophthalic acid.

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A metal-organic nanotube (MONT) was assembled by bridging the truncated metal-calixarene octahedra with coordinating water molecules. Remarkably, the tubular compound exhibited a much higher sorption capacity for C2H6 and C3H8… Click to show full abstract

A metal-organic nanotube (MONT) was assembled by bridging the truncated metal-calixarene octahedra with coordinating water molecules. Remarkably, the tubular compound exhibited a much higher sorption capacity for C2H6 and C3H8 than for CH4, and hence represents a promising material for separating these gases. The addition of a little NiSO4 into the reaction system led to the formation of a 2D metal-calixarene network.

Keywords: coordination nanotube; nanotube pyrimidin; pyrimidin isophthalic; calixarene; metal calixarene; calixarene coordination

Journal Title: Dalton transactions
Year Published: 2018

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