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A new system for cyclohexane functionalization employing iron(III) catalysts and trichloroisocyanuric acid

Herein, dinuclear and mononuclear iron complexes were investigated as catalysts in the reaction of cyclohexane chlorination employing trichloroisocyanuric acid as oxidant. At 25 °C, the yields provided by both catalysts… Click to show full abstract

Herein, dinuclear and mononuclear iron complexes were investigated as catalysts in the reaction of cyclohexane chlorination employing trichloroisocyanuric acid as oxidant. At 25 °C, the yields provided by both catalysts were similar (∼8%). However, at 50 °C, the mononuclear catalyst showed a better performance (34.4 ± 1.8%) than the binuclear catalyst (24.4 ± 1.0%).

Keywords: system cyclohexane; cyclohexane functionalization; trichloroisocyanuric acid; iron; new system; functionalization employing

Journal Title: New Journal of Chemistry
Year Published: 2017

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