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Synthesis of polysubstituted 3,4-dihydro-2H-thiopyrans by regioselective annulation of 3,3-disubstituted allylic alcohols with a β-oxodithioester

Polyfunctionalized 3,4-dihydro-2H-thiopyrans were obtained in high yields via the regioselective annulation of 3,3-disubstituted allylic alcohols with a β-oxodithioester under BF3·Et2O catalysis. Click to show full abstract

Polyfunctionalized 3,4-dihydro-2H-thiopyrans were obtained in high yields via the regioselective annulation of 3,3-disubstituted allylic alcohols with a β-oxodithioester under BF3·Et2O catalysis.

Keywords: regioselective annulation; annulation disubstituted; dihydro thiopyrans; allylic alcohols; disubstituted allylic; alcohols oxodithioester

Journal Title: New Journal of Chemistry
Year Published: 2017

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