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Transition-metal-free, visible-light-mediated cyclization of o-azidoarylalkynes with aryl diazonium salts

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Visible light along with 3 mol% eosin Y catalyzes the cyclization reaction of o-azidoarylalkynes with aryl diazonium salts by a photoredox process. We have investigated the scope of the reaction… Click to show full abstract

Visible light along with 3 mol% eosin Y catalyzes the cyclization reaction of o-azidoarylalkynes with aryl diazonium salts by a photoredox process. We have investigated the scope of the reaction for several aryl diazonium salts and o-azidoarylalkynes. The general and easy procedure provides a transition-metal-free alternative for the formation of unsymmetrical 2,3-diaryl-substitued indoles.

Keywords: azidoarylalkynes aryl; transition metal; visible light; diazonium salts; aryl diazonium

Journal Title: New Journal of Chemistry
Year Published: 2017

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