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We report an electrochemical method to deposit atomic scale Pt on a 5 nm Au nanoparticle (NP) surface in N2-saturated 0.5 M H2SO4. Pt is provided by the Pt wire… Click to show full abstract
We report an electrochemical method to deposit atomic scale Pt on a 5 nm Au nanoparticle (NP) surface in N2-saturated 0.5 M H2SO4. Pt is provided by the Pt wire counter electrode via one-step Pt wire oxidation, dissolution, and deposition realized by controlled electrochemical scanning. Scanning from 0.6-1.0 V (vs. RHE) for 10 000 cycles gives Au98.2Pt1.8, which serves as an excellent catalyst for the formic acid oxidation reaction, showing 41 times higher specific activity (20.19 mA cm-2) and 25 times higher mass activity (10.80 A mgPt-1) with much better CO-tolerance and stability than commercial Pt. Our work demonstrates a unique strategy to minimize the use of Pt as a catalyst for electrochemical reactions.
Journal Title: Nanoscale
Year Published: 2017
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