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Looped flow RAFT polymerization for multiblock copolymer synthesis

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A looped flow process was designed for the synthesis of well-defined multiblock copolymers using reversible addition–fragmentation chain transfer (RAFT) polymerization. The reaction conditions were optimized to reach high conversions whilst… Click to show full abstract

A looped flow process was designed for the synthesis of well-defined multiblock copolymers using reversible addition–fragmentation chain transfer (RAFT) polymerization. The reaction conditions were optimized to reach high conversions whilst maintaining a high end-group fidelity. The loop set-up proved to be a flexible, robust and time-efficient process for scaling-up multiblock copolymers.

Keywords: flow raft; multiblock; raft polymerization; looped flow

Journal Title: Polymer Chemistry
Year Published: 2017

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