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Triphenylene-based self-assembly modules, bearing three amide groups at the 1-, 5-, and 9-positions, were designed and synthesized. Supramolecular gels could be constructed by combining hydrogen bonding, π–π stacking and van… Click to show full abstract
Triphenylene-based self-assembly modules, bearing three amide groups at the 1-, 5-, and 9-positions, were designed and synthesized. Supramolecular gels could be constructed by combining hydrogen bonding, π–π stacking and van der Waals interactions. In addition, the assembly exhibited liquid crystalline mesophases by tuning of the length of the alkyl chains. This work provides an essential representative of functional assembly based on C3-symmetric triphenylenes.
Keywords:
synthesis self;
assembly unconventional;
self assembly;
unconventional symmetrical;
symmetrical trisubstituted;
trisubstituted triphenylenes
Journal Title: Materials Chemistry Frontiers
Year Published: 2017
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Journal Title: Materials Chemistry Frontiers
Year Published: 2017
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!