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Visible light-induced tandem oxidative cyclization of 2-alkynylanilines with disulfides (diselenides) to 3-sulfenyl- and 3-selenylindoles under transition metal-free and photocatalyst-free conditions

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A simple and efficient strategy for the synthesis of 3-sulfenyl and 3-selenyl indoles via a visible light-induced tandem cyclization of 2-alkynylanilines with disulfides (diselenides) was developed. The reaction generated the… Click to show full abstract

A simple and efficient strategy for the synthesis of 3-sulfenyl and 3-selenyl indoles via a visible light-induced tandem cyclization of 2-alkynylanilines with disulfides (diselenides) was developed. The reaction generated the corresponding products in good yields at room temperature under transition metal-free and photocatalyst-free conditions.

Keywords: cyclization alkynylanilines; light induced; disulfides diselenides; visible light; alkynylanilines disulfides; induced tandem

Journal Title: Organic chemistry frontiers
Year Published: 2017

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