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We report the first allylic isomerization of alcohols catalyzed by nBu4NOTf generated in situ from tetrabutylammonium triflate and potassium tert-butoxide. Substituted ketones could be prepared under mild conditions in good… Click to show full abstract
We report the first allylic isomerization of alcohols catalyzed by nBu4NOTf generated in situ from tetrabutylammonium triflate and potassium tert-butoxide. Substituted ketones could be prepared under mild conditions in good to excellent yields. The relationship between catalysts and their reactivity has been investigated by systematic kinetic studies. The radical nature of this isomerization reaction has also been confirmed.
Keywords:
promoted radical;
radical self;
self hydrogen;
isomerization;
bu4notf promoted;
hydrogen transferring
Journal Title: Organic chemistry frontiers
Year Published: 2018
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Journal Title: Organic chemistry frontiers
Year Published: 2018
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!