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An octupolar bis(porphyrinato) terbium(III) complex with the highest off-resonant hyperpolarizability

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A novel bis(porphyrinato) terbium double-decker complex HTb(DADAPor)2 with a twisted cuboid octupolar molecular symmetry exhibits the largest off-resonant first hyperpolarizability, as evaluated by harmonic light scattering measurements with = 1700… Click to show full abstract

A novel bis(porphyrinato) terbium double-decker complex HTb(DADAPor)2 with a twisted cuboid octupolar molecular symmetry exhibits the largest off-resonant first hyperpolarizability, as evaluated by harmonic light scattering measurements with = 1700 × 10−30 esu.

Keywords: bis porphyrinato; octupolar bis; porphyrinato terbium; terbium iii; iii complex; hyperpolarizability

Journal Title: RSC Advances
Year Published: 2017

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