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Performance of palladium–tin bimetallic catalysts supported on activated carbon for the hydrodechlorination of 4-chlorophenol

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The influence of Sn on the activity and selectivity of Pd catalysts for the hydrodechlorination (HDC) of 4-chlorophenol (CP) in an aqueous phase was studied. The Pd–Sn bimetallic catalysts were… Click to show full abstract

The influence of Sn on the activity and selectivity of Pd catalysts for the hydrodechlorination (HDC) of 4-chlorophenol (CP) in an aqueous phase was studied. The Pd–Sn bimetallic catalysts were prepared using the coimpregnation method and characterised using temperature-programmed reduction, high-resolution transmission electron microscopy, X-ray photoelectron spectroscopy, and hydrogen pulse chemisorption measurements. The results showed that when the molar ratio of Sn/Pd is less than 1/1, the addition of Sn to Pd catalysts improves the dispersibility of Pd particles and improves the catalytic activity of HDC.

Keywords: performance palladium; hydrodechlorination; palladium tin; bimetallic catalysts; catalysts supported; tin bimetallic

Journal Title: RSC Advances
Year Published: 2017

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