The nickel-catalyzed aminocarbonylation of aryl halides using carbamoylsilane as an amide source is developed. The procedure can prepare both tertiary and secondary amides, and is applicable to various carbamoylsilanes and… Click to show full abstract
The nickel-catalyzed aminocarbonylation of aryl halides using carbamoylsilane as an amide source is developed. The procedure can prepare both tertiary and secondary amides, and is applicable to various carbamoylsilanes and aryl halides containing different functional groups. The types and the relative position of substituents on the aryl ring impact the coupling efficiency.
Keywords:
catalyzed aminocarbonylation;
halides using;
aminocarbonylation aryl;
aryl halides;
using carbamoylsilane;
nickel catalyzed
Journal Title: RSC Advances
Year Published: 2017
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Journal Title: RSC Advances
Year Published: 2017
Link to full text (if available)
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recommendations!