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Deep oxidative desulfurization catalyzed by (NH4)xH4−xPMo11VO40 (x = 1, 2, 3, 4) using O2 as an oxidant

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NH4+ doped PMoV composites catalytic materials are successfully prepared. The NH4+ doped H4PMo11VO40 composites have been tested as highly efficient catalysts in the ultra-deep desulfurization of fuel oils. The reaction… Click to show full abstract

NH4+ doped PMoV composites catalytic materials are successfully prepared. The NH4+ doped H4PMo11VO40 composites have been tested as highly efficient catalysts in the ultra-deep desulfurization of fuel oils. The reaction conditions are optimized by testing the load of NH4+, temperature, O2 flow velocity, and DBT concentrations. The optimal reaction conditions are given as follows: 0.1 g (NH4)3HPMo11VO40 as catalyst, reaction time 2 h, O2 flow velocity 100 mL min−1, and reaction temperature 120 °C, with a conversion of DBT reaching up to 100% in 90 min, and this catalyst could be used more than five times without significant loss of activity.

Keywords: desulfurization; catalyzed nh4; reaction; oxidative desulfurization; deep oxidative; desulfurization catalyzed

Journal Title: RSC Advances
Year Published: 2017

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