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Thermoregulated phase-separable rhodium nanoparticle catalyst for selective hydrogenation of α,β-unsaturated aldehydes and ketones

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Thermoregulated phase-separable Rh nanoparticles (abbreviated as TPS-Rhnano) were found to be efficient catalysts for selective hydrogenation of CC bonds in α,β-unsaturated aldehydes and ketones with a selectivity of >99% at… Click to show full abstract

Thermoregulated phase-separable Rh nanoparticles (abbreviated as TPS-Rhnano) were found to be efficient catalysts for selective hydrogenation of CC bonds in α,β-unsaturated aldehydes and ketones with a selectivity of >99% at >99% conversion. More importantly, the catalyst could be easily separated by simple phase separation and reused directly eight times without evident loss in activity and selectivity.

Keywords: unsaturated aldehydes; phase; thermoregulated phase; selective hydrogenation; aldehydes ketones; phase separable

Journal Title: RSC Advances
Year Published: 2017

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