"New activation mechanism for half-sandwich organometallic anticancer complexes† †Electronic supplementary information (ESI) available. CCDC 1420046–1420052 and 1569283. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc05058e"

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New activation mechanism for half-sandwich organometallic anticancer complexes† †Electronic supplementary information (ESI) available. CCDC 1420046–1420052 and 1569283. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc05058e

Half-sandwich RhIII anticancer complexes with activated Cp* rings not only undergo sequential CH3 H–D exchange, but also react with biological dienes, generating RhI Diels–Alder adducts in aqueous media at ambient… Click to show full abstract

Keywords: activation mechanism; half sandwich; anticancer complexes; new activation

Journal Title: Chemical Science
Year Published: 2018

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