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A processing route for bulk, high coercivity, rare-earth free, nanocomposite magnets based on metastable iron oxide

High coercivity magnets are crucial in technology today, but dependence on rare earth elements and/or precious metals limits the application of the state of the art magnets. Here we introduce… Click to show full abstract

High coercivity magnets are crucial in technology today, but dependence on rare earth elements and/or precious metals limits the application of the state of the art magnets. Here we introduce a method for producing large sized nanocomposite magnets comprised primarily of a metastable material. They have a very high coercivity (∼12 kOe) and are based on three of the most earth abundant elements—Fe, Si and O. The key is leveraging length scale and kinetic control to stabilize a large volume content of the metastable e-Fe2O3 nanophase in a thin silica matrix to obtain a high density of magnetic phase. X-ray diffraction, electron microscopy and magnetic measurements confirm densely packed nanorods consisting primarily of e-Fe2O3. These nanocomposites have some of the highest coercivities reported in dense millimeter-sized magnets that do not contain rare earths or precious metals.

Keywords: nanocomposite magnets; rare earth; coercivity; processing route; high coercivity

Journal Title: Journal of Materials Chemistry C
Year Published: 2017

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