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Light-enhanced acid catalysis over a metal-organic framework.

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A Brønsted acid-functionalized metal-organic framework (MOF), MIL-101-SO3H, was prepared for acid-engaged esterification reactions. Strikingly, for the first time, the MOF exhibits significantly light-enhanced activity and possesses excellent activity and recyclability,… Click to show full abstract

A Brønsted acid-functionalized metal-organic framework (MOF), MIL-101-SO3H, was prepared for acid-engaged esterification reactions. Strikingly, for the first time, the MOF exhibits significantly light-enhanced activity and possesses excellent activity and recyclability, with even higher activity than H2SO4 under light irradiation.

Keywords: enhanced acid; light enhanced; metal organic; organic framework

Journal Title: Chemical communications
Year Published: 2018

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