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Photoredox generation of the trifluoromethyl radical from borate complexes via single electron reduction.

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A method for the generation of the CF3 radical from CF3-substituted borate complexes bearing a pyridine-N-oxide ligand is described. Cleavage of the C-B bond occurs via single electron reduction by… Click to show full abstract

A method for the generation of the CF3 radical from CF3-substituted borate complexes bearing a pyridine-N-oxide ligand is described. Cleavage of the C-B bond occurs via single electron reduction by a Cu(i) photocatalyst activated by visible light.

Keywords: single electron; electron reduction; generation; via single; borate complexes

Journal Title: Chemical communications
Year Published: 2018

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