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Room-temperature optic-electric duple bistabilities induced by plastic transition.

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We disclosed that acetamidinium perchlorate is a plastic crystal undergoing a near-room-temperature plastic transition. Thanks to drastic symmetry breaking during the plastic transition, it displays remarkable nonlinear optical switching with… Click to show full abstract

We disclosed that acetamidinium perchlorate is a plastic crystal undergoing a near-room-temperature plastic transition. Thanks to drastic symmetry breaking during the plastic transition, it displays remarkable nonlinear optical switching with a high on/off contrast and a superior reversibility, as well as rapid dielectric switching between the high and low dielectric states.

Keywords: plastic transition; temperature optic; transition; room temperature

Journal Title: Chemical communications
Year Published: 2018

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