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Intermolecular insertion reactions of azides into 9-borafluorenes to generate 9,10-B,N-phenanthrenes.

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The reactions of 9-borafluorenes with organic azides result in either the insertion of the α-nitrogen and elimination of N2 or the insertion of the γ-nitrogen to generate the corresponding phenanthrene… Click to show full abstract

The reactions of 9-borafluorenes with organic azides result in either the insertion of the α-nitrogen and elimination of N2 or the insertion of the γ-nitrogen to generate the corresponding phenanthrene analogues with boron and nitrogen in the 9- and 10-positions, respectively.

Keywords: insertion reactions; insertion; borafluorenes generate; reactions azides; intermolecular insertion; azides borafluorenes

Journal Title: Chemical communications
Year Published: 2018

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