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Combining a pyclen framework with conjugated antenna for the design of europium and samarium luminescent bioprobes.

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The first pyclen based ligand bearing two picolinate intra-ligand charge transfer transition antennae and one acetate arm organized in a dissymmetric manner was synthesized for Eu(iii) and Sm(iii) complexation. The… Click to show full abstract

The first pyclen based ligand bearing two picolinate intra-ligand charge transfer transition antennae and one acetate arm organized in a dissymmetric manner was synthesized for Eu(iii) and Sm(iii) complexation. The europium complex presents an excellent brightness and biphotonic imaging of T24-cells has been performed using Eu(iii) and the less common Sm(iii) bioprobes.

Keywords: framework conjugated; conjugated antenna; europium; antenna design; combining pyclen; pyclen framework

Journal Title: Chemical communications
Year Published: 2018

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