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Low-overpotential CO2 reduction by a phosphine-substituted Ru(ii) polypyridyl complex.

A Ru polypyridyl complex containing a phosphine donor promoted electrocatalytic CO2 reduction at a low overpotential. Mechanistic investigations revealed that the introduction of a phosphine donor at the trans position… Click to show full abstract

A Ru polypyridyl complex containing a phosphine donor promoted electrocatalytic CO2 reduction at a low overpotential. Mechanistic investigations revealed that the introduction of a phosphine donor at the trans position to the labile ligand is the key to reduce the overpotential for CO2 reduction.

Keywords: co2 reduction; low overpotential; polypyridyl complex; phosphine; overpotential co2

Journal Title: Chemical communications
Year Published: 2018

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