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C-C to C[double bond, length as m-dash]C conversion within a supramolecular framework of tetrathiafulvalene: a confinement effect and an oxygen related dehydrogenation.

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Dehydrogenation of alkanes to generate alkenes is catalyzed by a supramolecular framework of a tetrathiafulvalene derivative under ambient conditions, and a confinement effect of the framework is responsible for the… Click to show full abstract

Dehydrogenation of alkanes to generate alkenes is catalyzed by a supramolecular framework of a tetrathiafulvalene derivative under ambient conditions, and a confinement effect of the framework is responsible for the oxidation reaction in the presence of oxygen.

Keywords: dehydrogenation; framework; framework tetrathiafulvalene; supramolecular framework; confinement effect

Journal Title: Chemical communications
Year Published: 2018

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