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Unexpected halide anion binding modes in meso-bis-ethynyl picket-calix[4]pyrroles: effects of meso-π (ethynyl) extension.

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meso-Ethynyl extended aryl-picket calix[4]pyrroles 2 and 3 are designed and synthesized by directly anchoring arylethynyl groups at diametrically opposed meso-positions. The critical roles of direct ethynyl linkers are manifested through… Click to show full abstract

meso-Ethynyl extended aryl-picket calix[4]pyrroles 2 and 3 are designed and synthesized by directly anchoring arylethynyl groups at diametrically opposed meso-positions. The critical roles of direct ethynyl linkers are manifested through the isolation of unexpected host-anion conformers of meso-arylethynyl calix[4]pyrroles and a significant enhancement in halide binding affinities.

Keywords: meso ethynyl; picket calix; calix; calix pyrroles

Journal Title: Chemical communications
Year Published: 2018

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