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Disilanylene-bridged BODIPY-based D-σ-A architectures: a novel promising series of NLO chromophores.

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The synthesis and optical properties of a novel series of disilanylene-bridged BODIPY-based D-σ-A chromophores are reported. Si-Si σ-electrons are useful and impressible for tunable optical properties. The electron-donating group facilitates… Click to show full abstract

The synthesis and optical properties of a novel series of disilanylene-bridged BODIPY-based D-σ-A chromophores are reported. Si-Si σ-electrons are useful and impressible for tunable optical properties. The electron-donating group facilitates enhancement of the CT nature of the excited state through σ(Si-Si) orbital, leading to the remarkable two-photon absorption cross-sections.

Keywords: bodipy based; disilanylene bridged; series; architectures novel; bridged bodipy; based architectures

Journal Title: Chemical communications
Year Published: 2018

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