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The electronic structure of f-element Prussian blue analogs determined by soft X-ray absorption spectroscopy.

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In molecular solids derived from Prussian blue, intermetallic charge transfer is fostered through a cyano bridge two metal ions. In this study, isostructural trivalent lanthanide and tetravalent actinide Prussian blue… Click to show full abstract

In molecular solids derived from Prussian blue, intermetallic charge transfer is fostered through a cyano bridge two metal ions. In this study, isostructural trivalent lanthanide and tetravalent actinide Prussian blue analogs' valence orbitals are probed by soft X-ray absorption measurements.

Keywords: ray absorption; blue analogs; prussian blue; spectroscopy; soft ray

Journal Title: Chemical communications
Year Published: 2018

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