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Mechanochromic luminescent covalent organic frameworks for highly selective hydroxyl radical detection.

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The mechanochromic luminescence phenomenon was first reported in the low-cost mechanochemical (MC) synthesis process of a covalent organic framework (COF-TpMA (MC)) prepared using triformylphloroglucinol (Tp) and melamine (MA) as precursors,… Click to show full abstract

The mechanochromic luminescence phenomenon was first reported in the low-cost mechanochemical (MC) synthesis process of a covalent organic framework (COF-TpMA (MC)) prepared using triformylphloroglucinol (Tp) and melamine (MA) as precursors, which shows excellent performance as a hydroxyl radical (˙OH) detector in living systems. This work not only shows a new kind of mechanochromic luminescent material but also exhibits a close relationship between the π-π stacking and luminescence properties of COF materials.

Keywords: hydroxyl radical; luminescent covalent; covalent organic; mechanochromic luminescent

Journal Title: Chemical communications
Year Published: 2018

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