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Bronze alloys with tin surface sites for selective electrochemical reduction of CO2.

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Low concentration tin bronze alloys show high selectivity for CO2 electroreduction to CO, while high concentration tin bronze alloys show high selectivity for formate. The tin surface sites appear to… Click to show full abstract

Low concentration tin bronze alloys show high selectivity for CO2 electroreduction to CO, while high concentration tin bronze alloys show high selectivity for formate. The tin surface sites appear to control selectivity by influencing the binding characteristics toward the first reaction intermediate on copper-based alloys.

Keywords: co2; surface sites; bronze alloys; tin surface

Journal Title: Chemical communications
Year Published: 2018

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