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Exploring ligand non-innocence of coordinatively-versatile diamidodipyrrinato cobalt complexes.

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The non-innocence of diamidodipyrrin is explored in a series of cobaltous complexes with novel binding motifs. By varying the coordination modes, a reversible one-electron reduction is remarkably shifted by nearly… Click to show full abstract

The non-innocence of diamidodipyrrin is explored in a series of cobaltous complexes with novel binding motifs. By varying the coordination modes, a reversible one-electron reduction is remarkably shifted by nearly 200 mV in a single metal-ligand platform. Our study illustrates a new strategy for modifying the redox activity of porphyrin-like scaffolds.

Keywords: non innocence; ligand non; exploring ligand; innocence; innocence coordinatively

Journal Title: Chemical communications
Year Published: 2019

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