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Hydroxyl free radical route to the stable siliceous Ti-UTL with extra-large pores for oxidative desulfurization.

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A facile and mild method was successfully developed to prepare the stable, highly siliceous Ti-UTL zeolite with extra-large pores. The hydroxyl free radical (˙OH) was introduced for the first time… Click to show full abstract

A facile and mild method was successfully developed to prepare the stable, highly siliceous Ti-UTL zeolite with extra-large pores. The hydroxyl free radical (˙OH) was introduced for the first time to effectively promote the isomorphous substitution of Si for framework Ge under room temperature and neutral conditions, resulting in a stable titanosilicate with an outstanding catalytic activity for oxidative desulfurization.

Keywords: siliceous utl; free radical; hydroxyl free; large pores; extra large; oxidative desulfurization

Journal Title: Chemical communications
Year Published: 2019

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