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Stepwise degradation of hydroxyl compounds to aldehydes via successive C-C bond cleavage.

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Stepwise degradation of hydroxyl compounds to aldehydes via successive cleavage of C-C bonds was achieved by using a bimetallic catalytic system (PdCl2 + CuCl) without any ligands and additives. The… Click to show full abstract

Stepwise degradation of hydroxyl compounds to aldehydes via successive cleavage of C-C bonds was achieved by using a bimetallic catalytic system (PdCl2 + CuCl) without any ligands and additives. The broad applicability is expanded to a diverse range of aromatic, aliphatic, primary and secondary alcohols, as well as lignin model compounds.

Keywords: aldehydes via; compounds aldehydes; via successive; stepwise degradation; degradation hydroxyl; hydroxyl compounds

Journal Title: Chemical communications
Year Published: 2019

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