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Lowering the charge overpotential of Li2S via the inductive effect of phenyl diselenide in Li-S batteries.

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We find that phenyl diselenide (PDSe) can lower the charge overpotential of Li2S via an inductive effect. The Se-Se bond of PDSe can break when it is in contact with… Click to show full abstract

We find that phenyl diselenide (PDSe) can lower the charge overpotential of Li2S via an inductive effect. The Se-Se bond of PDSe can break when it is in contact with Li2S. The attraction between Se and Li weakens the Li-S bonds and facilitates the oxidation of Li2S in lithium batteries.

Keywords: charge overpotential; overpotential li2s; li2s via; phenyl diselenide; via inductive; li2s

Journal Title: Chemical communications
Year Published: 2019

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