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Herein we present the synthesis and characterisation of the seven-membered group 13/15 chain compound HB{N(H)PtBu2BH3}2 (3) obtained from the reaction of tBu2PNH2 (1) with Me2S·BH3. Furthermore, we describe the synthesis… Click to show full abstract
Herein we present the synthesis and characterisation of the seven-membered group 13/15 chain compound HB{N(H)PtBu2BH3}2 (3) obtained from the reaction of tBu2PNH2 (1) with Me2S·BH3. Furthermore, we describe the synthesis of the aluminium and gallium compounds tBu2PN(H)AltBu2N(H)P(H)tBu2 (4) and tBu2(H)PN(H)GatBu3 (5) derived from the reaction of tBu2PNH2 (1) with MtBu3 (M = Al, Ga).
Keywords:
chain compounds;
ternary group;
group;
group chain;
synthesis ternary
Journal Title: Dalton transactions
Year Published: 2018
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Journal Title: Dalton transactions
Year Published: 2018
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!