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Zirconium complexes stabilized by amine-bridged bis(phenolato) ligands showed good activity and chemo-selectivity in catalyzing intermolecular hydrophosphination of C-C multiple bonds with primary phosphines under mild conditions. A broad range of… Click to show full abstract
Zirconium complexes stabilized by amine-bridged bis(phenolato) ligands showed good activity and chemo-selectivity in catalyzing intermolecular hydrophosphination of C-C multiple bonds with primary phosphines under mild conditions. A broad range of alkenes and alkynes underwent a mono-addition reaction with phenylphosphine, which generated secondary phosphines in 39-99% yields and >7 : 1 selectivity (over double hydrophosphination).
Keywords:
zirconium complexes;
primary phosphines;
hydrophosphination alkenes;
hydrophosphination;
alkenes alkynes
Journal Title: Dalton transactions
Year Published: 2018
Link to full text (if available)
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Journal Title: Dalton transactions
Year Published: 2018
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!