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The present study describes the first example of the stoichiometric and catalytic oxidation of flavanone by synthetic nonheme oxoiron(iv) complexes and their precursor iron(ii) complexes with m-CPBA as the terminal… Click to show full abstract
The present study describes the first example of the stoichiometric and catalytic oxidation of flavanone by synthetic nonheme oxoiron(iv) complexes and their precursor iron(ii) complexes with m-CPBA as the terminal oxidant. These models, including detailed kinetic, mechanistic and computational studies, may serve as the biomimics of flavone synthase (FS) enzymes.
Keywords:
flavone synthase;
oxoiron complexes;
kinetic mechanistic;
mechanistic computational;
nonheme oxoiron;
computational studies
Journal Title: Dalton transactions
Year Published: 2018
Link to full text (if available)
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Journal Title: Dalton transactions
Year Published: 2018
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!