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Effect of substituents on molybdenum triiodide complexes bearing PNP-type pincer ligands toward catalytic nitrogen fixation.

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Molybdenum triiodide complexes bearing various substituted pyridine-based PNP-type pincer ligands are prepared and characterized by X-ray analysis. Their catalytic activity is investigated toward the reduction of nitrogen gas into ammonia… Click to show full abstract

Molybdenum triiodide complexes bearing various substituted pyridine-based PNP-type pincer ligands are prepared and characterized by X-ray analysis. Their catalytic activity is investigated toward the reduction of nitrogen gas into ammonia under ambient reaction conditions.

Keywords: pnp type; molybdenum triiodide; pincer ligands; triiodide complexes; type pincer; complexes bearing

Journal Title: Dalton transactions
Year Published: 2019

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