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The redox chemistry of the first stable anionic dithiolene radical 1˙ was investigated by both reactivity and cyclic voltammetry studies. While one-electron reduction of 1˙ by Cp2Co or KC8 affords… Click to show full abstract
The redox chemistry of the first stable anionic dithiolene radical 1˙ was investigated by both reactivity and cyclic voltammetry studies. While one-electron reduction of 1˙ by Cp2Co or KC8 affords the corresponding dithiolate dimers 2 and 3, respectively, one-electron oxidation of 1˙ by Ph3C+BF4- (or O2) conveniently gives 4, the neutral dithiolene dimer.
Keywords:
chemistry anionic;
redox chemistry;
chemistry;
dithiolene;
anionic dithiolene;
dithiolene radical
Journal Title: Dalton transactions
Year Published: 2019
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Journal Title: Dalton transactions
Year Published: 2019
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!