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Highly active NHC–Pd(II) complexes for cross coupling of aryl chlorides and arylboronic acids: an investigation of the effect of remote bulky groups

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A series of palladium(II) complexes bearing remote bulky ligands were synthesized and characterized. Their catalytic activity for Suzuki–Miyaura cross-coupling reactions and the effect of remote bulky groups were investigated. These… Click to show full abstract

A series of palladium(II) complexes bearing remote bulky ligands were synthesized and characterized. Their catalytic activity for Suzuki–Miyaura cross-coupling reactions and the effect of remote bulky groups were investigated. These new palladium complexes are highly efficient for the Suzuki–Miyaura cross-coupling reactions of aryl chlorides and arylboronic acids with low catalyst loadings (0.05 mol%) at room temperature in air.

Keywords: effect remote; bulky groups; remote bulky; aryl chlorides; cross coupling

Journal Title: New Journal of Chemistry
Year Published: 2018

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