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Palladium-catalyzed construction of amidines from arylsilanes in the absence of a ligand under oxidative conditions

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An interesting palladium-catalyzed procedure for the synthesis of amidines from arylsilanes, isocyanides and amines has been developed. Moderate to good yields of the desired amidines were produced in the absence… Click to show full abstract

An interesting palladium-catalyzed procedure for the synthesis of amidines from arylsilanes, isocyanides and amines has been developed. Moderate to good yields of the desired amidines were produced in the absence of a phosphine ligand under oxidative conditions.

Keywords: construction amidines; oxidative conditions; amidines arylsilanes; catalyzed construction; palladium catalyzed; ligand oxidative

Journal Title: New Journal of Chemistry
Year Published: 2018

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