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Probing Lewis acid-base interactions in single-molecule junctions.

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A novel strategy to regulate the tunneling mechanism for charge transport through an organoborane wire via Lewis acid-base interactions has been developed. A change from LUMO- to HOMO-dominated charge transport… Click to show full abstract

A novel strategy to regulate the tunneling mechanism for charge transport through an organoborane wire via Lewis acid-base interactions has been developed. A change from LUMO- to HOMO-dominated charge transport upon the addition of the fluoride is verified both experimentally and theoretically.

Keywords: interactions single; lewis acid; acid base; probing lewis; base interactions

Journal Title: Nanoscale
Year Published: 2018

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